The four major performance indicators of
prepreg are: resin content, soluble resin content, volatile matter content, and
fluidity.
1.Effect of resin content on
electromechanical property
The dielectric properties of laminates
increase with the increase in resin content. When the resin content is
increased to a certain value, the resin content will not increase below 60%.
When the resin content increases, the electrical performance will increase.
When it reaches 60%, the resin content will increase and the electrical
performance will increase. The improvement is not obvious. The resin content
also affects the mechanical and physical properties of epoxy boards. The
mechanical properties of epoxy laminates increase as the resin content
increases, but the optimal value of mechanical strength appears when a certain
value is reached, and then increases with the resin content Instead, the
mechanical strength decreases. When the resin content is less than 35%, the
mechanical properties are reduced, and it is considered that the adhesion is
not good; when the resin content is more than 35%, as the resin content
increases, the effect of the resin is prominent, and the strength of the resin
is lower than that of the reinforcing material. many. For example, the tensile strength
of phenolic resin is only 35 ~ 50MPa, and the epoxy resin is 65 ~ 80MPa; the
impact strength is lower, such as epoxy resin is 10 ~ 20kJ / m2; the mechanical
strength of reinforcing materials is very high, such as electrical Glass fiber
single yarn has a tensile strength of 50MPa.
The resin content also has a greater effect
on the water absorption and relative density of the laminate. As the resin
content increases, the voids of the reinforcing material in the laminate are
filled by the resin. Water absorption of phenolic resin is 0.12% ~ 0.36%, and
epoxy resin is 0.10%. The water absorption of the laminate decreases with the
increase of the resin content, but when the resin fills all the voids of the
fiber material, the water absorption reaches a constant value and does not
decrease any more. The relative density of the laminate decreases with
increasing resin content, which is determined by the relative density of the
resin. For example, the relative density of phenolic resin is 1.30 ~ 1.32, and
the relative density of epoxy resin is 1.15. Epoxy laminate is a composite of
resin and reinforcing material, so its performance is related to the ratio of
the two. Generally, the resin content of the prepreg required for laminates
that require electrical properties is larger; the resin content is required to
be smaller for those that require high mechanical properties. Generally, the
glass cloth laminate is controlled at about 40%, because Flow glue and
volatiles overflow
2.Effect of soluble resin content on performance
The soluble resin content refers to the
mass fraction of the resin that can be dissolved in the solvent in the prepreg.
If the content of the soluble resin is large, the prepreg is relatively tender.
If the content of the soluble resin is small, the pre-dip stain is old. The
soluble resin content is large, the resin fluidity is large, the penetration
ability is strong, and the adhesiveness is excellent, but the glue is easy to
flow during pressing, if the pressing is too fast, it is easy to cause the
stack and steel plate to slip out from the hot plate of the press The pressing
time should be increased accordingly. At the same time, the pressure should be
moderately released during the preheating stage (open the hot plate) to ensure
that the volatiles overflow. The soluble resin content is small, the adhesion
is not good, the mechanical strength is severely reduced, and the laminate is
cracked between layers.
3.Effect of volatile content on the property
of laminates
The volatile content of prepreg refers to
the mass ratio of volatile substances, such as water, solvents, and low
molecular substances, remaining in the prepreg to the prepreg. The volatile
content has a significant effect on the electrical properties of the laminate.
The volatiles content increased from 4% to 5%, and its tan6 doubled. Its
dielectric strength and internal resistance both decreased due to the large
volatiles. Not only that, but also makes the thermal deformation temperature of
the laminate lower, which causes defects such as blistering, cracking and
surface pattern of the laminate. Therefore, the pressure should be lowered
during preheating, and the temperature will rise a little faster, so that its
volatiles will easily overflow, and the pressure will be gradually increased
during the hot pressing stage
Therefore, the prepreg should be stored in
a constant temperature, humidity and dust-free warehouse.
4. As for the fluidity, it is similar to
the soluble resin content, but because the test method is more intuitive, it
has a guiding effect on the pressing process, and the effect on product
performance is similar to the soluble resin content.